Book on Chemical Thermodynamics

In summary, the conversation is about the speaker struggling with chapter five of the book "An Introduction to Thermal Physics" by Daniel Schroeder, specifically the section on chemical thermodynamics. They are looking for another book to gain a different perspective on the material. The speaker mentions their confusion with the equation μ(T,P) = μ^0(T)+ kTln(\frac{P}{P^0}) and how it is derived from Gibbs free energy. They also mention their difficulty in applying this equation to exercises involving an inert gas added to a system with a reactive gas in equilibrium with its liquid phase. The equation is also used to deduce Raoult's law. The speaker also mentions their lack of understanding on osmotic pressure,
  • #1
Avatrin
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Hi
I am currently using a book called "An Introduction to Thermal Physics" by Daniel Schroeder, and there is a part of the book I am struggling with. So, I am looking for some other book that can help me learn the same stuff (to get a different perspective on the same material). For people familiar with the book, I am struggling with chapter five. For those who are not:

It is a chapter on free energy and chemical thermodynamics. The part I am struggling with is the chemical thermodynamics. For instance, the parts he uses one equation in particular are odd to me (for ideal gasses):

[tex] μ(T,P) = μ^0(T)+ kTln(\frac{P}{P^0})[/tex]

He deduces this by using Gibbs free energy. I get the deduction, but I do not understand how to use it.

So, when he asks me to use this in exercises to understand what happens when, for instance, an inert gas is added to a system in which a reactive gas is in equilibrium with its liquid phase, I do not know what to do.

He uses the equation above to deduce Raoult's law.

I do not understand osmotic pressure, phase transitions of mixtures and Van't Hoff's formula.
 
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  • #2
Lewis & Randall, 2nd ed., revised by Pitzer & Brewer. Or, Irving Klotz.
 
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