Calculate \Delta H_{rxn}\circ for 2Al_{2}O_{3} to 4Al+3O_{2}

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The discussion centers on calculating the standard enthalpy change (\Delta H_{rxn}\circ) for the reaction 2Al_{2}O_{3}(s) → 4Al + 3O_{2}(g). The standard enthalpy of formation for Al_{2}O_{3} is given as -1670 kJ/mol. To find \Delta H_{rxn}\circ, one might initially think to multiply -1670 kJ/mol by 2, resulting in -3340 kJ/mol. However, the correct answer is actually +3340 kJ/mol. This discrepancy arises because reversing the reaction direction necessitates reversing the sign of the enthalpy change. Since the formation of Al_{2}O_{3} is exothermic, the decomposition into aluminum and oxygen is endothermic, thus resulting in a positive value for \Delta H_{rxn}\circ.
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\Delta H_{f}\circ=-1670kJ/mol for Al_{2}O_{3}

What is \Delta H_{rxn}\circ for
2Al_{2}O_{3}(s)\rightarrow4Al+3O_{2}(g)

So clearly we simply multiply -1670*2=-3340kJ/mol.

The answer is actually POSITIVE 3340kJ/mol!

Can someone please explain to me how this reasoning works?

Thank you!
 
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You reverse the reaction direction, so you need to reverse the sign. If reaction is exothermic when going one side, it must be endothermic when going back.
 
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