Calculating Heat of Solution for CaCl2 & NaHCO3: Equations and Solutions

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Discussion Overview

The discussion centers around the heat of solution for calcium chloride (CaCl2) and sodium bicarbonate (NaHCO3), exploring the definitions, calculations, and sources of information regarding these values. It involves aspects of homework and conceptual clarification.

Discussion Character

  • Homework-related, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant states that the heat of solution is formally known as the enthalpy of fusion, suggesting a potential misunderstanding.
  • Another participant corrects this by asserting that dissolution and fusion are distinct processes, clarifying that heat of solution refers to the heat evolved during dissolution.
  • A participant questions whether the heat of solution is a calculable value or if it can be found in a list of known values.
  • Another response indicates that heat of solution values are typically determined experimentally, and mentions that Hess's law could be used for calculations if other data is available.

Areas of Agreement / Disagreement

Participants express disagreement regarding the definitions of heat of solution and enthalpy of fusion, with some clarifying the distinction while others appear uncertain about the calculation methods and sources for these values.

Contextual Notes

There is a lack of consensus on the definitions and calculations related to the heat of solution, with some participants relying on experimental data while others seek lists or formulas.

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Homework Statement


What is the heat of solution of calcium chloride (CaCl2) and sodium bicarbonate (NaHCO3)?


Homework Equations





The Attempt at a Solution


Heat of solution is more formally known as the enthalpy of fusion. I tried googling this but I am not sure if this is the correct answer...
Heat of solution of CaCl2: -81.3 kJ/mol
Heat of solution of NaHCO3: +33 kJ/mol

Any help is appreciated! Any websites with such information would be awesome!
 
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jessica.so said:
Heat of solution is more formally known as the enthalpy of fusion.

No, dissolution and fusion are two separate processes. Heat of solution is heat that evolves during dissolution of a substance (usually in water). Heat of fusion is amount of heat required to melt the substance.
 
Okay. Is the heat of solution a value that I need to calculate that has a formula? Or should I be able to find a list that lists all of them?
 
Basically these are determined experimentally. If some other data is known it can be possible to calculate heat of dissolution from the Hess law, but the same can be told about every other process.
 

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