Calculating Mean Free Path of Molecules in a Test Tube

AI Thread Summary
To calculate the mean free path of molecules in a cylindrical test tube, the relevant equation is λ = 1 / (π * d^2 * n). Given the test tube dimensions and the number of molecules, the density n can be determined by dividing the total number of molecules by the volume of the test tube. The mean free path represents the average distance between collisions of the molecules, which is influenced by their size and density. The user is on the right track by attempting to apply the formula, but needs to ensure correct unit conversions and calculations for accurate results. Understanding the relationship between molecular size, density, and collision frequency is essential for solving this problem.
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Homework Statement


A test tube of cylindrical shape having a length of 10 cm and a diameter of 2 cm contains 20 * 10 ^23 molecules (molecular size d = 3 * 10^-10 m). What is the mean free path of these molecules??


Homework Equations


λ = 1/ pi * d^2 * n


The Attempt at a Solution


This is an equation I have never used before and my textbook doesn't help with either. I tried to solve it by:
1 / pi * (2 cm)^2 * (20 * 10^23 / 3*10^-12 cm)
I haven't ever done something like it before, am I on the right track with this?
 
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The mean free path is the distance between two subsequent collisions between the molecules. When the molecules touch each other, their centres are d distance apart (d is the diameter). The molecules are in motions and will collide with all molecules along their path get closer to centre -to centre than the diameter. Look at the blue molecule in the figure: When it travels along a path of length L it will collide with all molecules with centre confined in a cylinder of diameter 2d and length L.
If the density of molecules is n, the number of molecules in this cylinder is N= n*d^2*pi*L, there are N collisions along L length: the distance traveled between two subsequent collision is

\lambda = \frac{L}{N}= \frac{1}{d^2\pi n}

You know the number of the molecules in a known volume, so you can determine n.

ehild
 
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