To solve the equation arctan(3x) + arctan(2x) = π/4, the identity arctan[x] + arctan[y] = arctan[(x+y)/(1-xy)] is applied. This simplifies to finding the angle whose tangent is 1, leading to the equation 5x/(1-6x^2) = 1. Solving this results in x = 1/6 and x = -1, but -1 is rejected since it falls outside the domain of arctan. Therefore, the valid solution is x = 1/6.