The V/C characteristic of a Capacitor is a constant slope (the Capacitance. For a Lion battery, the drop in volts from near full to dying is pretty much a horizontal line. From full to usably empty, the battery volts only drop by around 10%. I can't see the similarity there.
I could imagine that, if weight is not a problem, with the battery fully charged, carrying some Capacitance could give you some advantage with acceleration for a short burst but, with the best will in the world, you can only get 10% of the charge in the Capacitor. But I don't see a problem with including some smart switching in a design that's obviously going to be a bit pricey in any case. (I'm only arguing against the simple idea of parallel connection.)
One point in favour of the SuperCapacitor is that the actual Energy capacity is all at the top of its voltage range ( Energy = (CV2/2) so you don't have to nearly discharge it. Any installation with SuperCs in it is going to have some fancy switching control in any case if the user is going to have any idea what the accelerator pedal will do for him.