Change in Enthelpy with no Heat Exchange?

Click For Summary
SUMMARY

In thermodynamics, a change in entropy can occur in a cycle without a net heat exchange, particularly in non-quasistatic and adiabatic processes. The principle of maximum entropy indicates that systems evolve towards equilibrium, even under adiabatic conditions. To calculate entropy change, the formula ΔS = ∫dQrev/T is utilized, requiring the identification of a reversible path between initial and final states. This discussion clarifies the relationship between entropy, heat exchange, and internal energy in thermodynamic cycles.

PREREQUISITES
  • Understanding of thermodynamic cycles
  • Familiarity with the principle of maximum entropy
  • Knowledge of adiabatic processes
  • Proficiency in integral calculus for thermodynamic equations
NEXT STEPS
  • Study the implications of non-quasistatic processes in thermodynamics
  • Learn about the calculation of entropy changes in adiabatic processes
  • Explore the concept of reversible paths in thermodynamic systems
  • Investigate the relationship between internal energy and entropy in closed systems
USEFUL FOR

Students studying thermodynamics, particularly those preparing for exams, as well as educators and professionals seeking to deepen their understanding of entropy and heat exchange in thermodynamic systems.

Zenderson3
Messages
2
Reaction score
0
This is a rather general question but I'm studying for my thermodynamics final and wanted to clarify this topic.

Is it possible for there to be a change in entropy in a cycle without a net exchange of heat into or out of the system? If so what may be some of the examples of this and how would (if you can) would you calculate this change.

I know the principle of maximum entropy describes that a system would evolve to the equilibrium point of maximum entropy but would it do this if it were adiabatic or does the change in internal energy need to remain constant?

Also I know that if a process is non-quasistatic and adiabatic the entropy will change but is there anyway to calculate this value?
 
Science news on Phys.org
Zenderson3 said:
This is a rather general question but I'm studying for my thermodynamics final and wanted to clarify this topic.

Is it possible for there to be a change in entropy in a cycle without a net exchange of heat into or out of the system? If so what may be some of the examples of this and how would (if you can) would you calculate this change.
In one complete cycle, a system returns to its original state. So its entropy must be the same. (did you mean enthalpy or entropy in your title?)

I know the principle of maximum entropy describes that a system would evolve to the equilibrium point of maximum entropy but would it do this if it were adiabatic or does the change in internal energy need to remain constant?
No sure what you are getting at. Can you give an example?

Also I know that if a process is non-quasistatic and adiabatic the entropy will change but is there anyway to calculate this value?
Sure. ΔS = ∫dQrev/T

You just need to determine the reversible path between the beginning and end states and calculate the integral along that path.

AM
 

Similar threads

  • · Replies 15 ·
Replies
15
Views
3K
  • · Replies 60 ·
3
Replies
60
Views
11K
  • · Replies 14 ·
Replies
14
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 22 ·
Replies
22
Views
6K
  • · Replies 15 ·
Replies
15
Views
3K
  • · Replies 8 ·
Replies
8
Views
2K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 13 ·
Replies
13
Views
4K
  • · Replies 1 ·
Replies
1
Views
2K