Change in Entropy and adiabatic process

In summary, if a process is adiabatic and reversible, such as a gas in a tube that has been compressed, there will be no change in entropy from the gas being uncompressed to being compressed. This is because there is no heat flow and the system is in equilibrium at all times. Therefore, dS=0 and there is no change in entropy.
  • #1
grscott_2000
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If a process is adiabatic and reversible, such as a gas in a tube that has been compressed, is it true to say that there is no change in entropy from the gas being uncompressed to being compressed?

If not, why not?
 
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  • #2
grscott_2000 said:
If a process is adiabatic and reversible, such as a gas in a tube that has been compressed, is it true to say that there is no change in entropy from the gas being uncompressed to being compressed?

If not, why not?
Entropy is defined as heat flow / temperature at equilibrium: dS = dQ/T. If the process is adiabatic and reversible, this means there is no heat flow and at all times the system is in equilibrium. So dQ=0. So that pretty much means that dS = 0 (ie. no change in entropy).

AM
 
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  • #3
You can see that without taking into account the equation dS=dQ/T.
The entropy of the gas in a cylinder is increased when its temperature is increased and the entropy is decreased when its volume is reduced. When you compress the cylinder of gas without heat exchange, its volume is reduced while its tempereture raises, so entropy is unchanged. dS=0
 

1. What is entropy?

Entropy is a measure of the disorder or randomness of a system. It is a thermodynamic property that describes the amount of energy that is unavailable for work in a system.

2. How is entropy related to adiabatic processes?

In an adiabatic process, there is no exchange of heat between the system and its surroundings. This means that any change in entropy is solely due to the work done on or by the system. As a result, adiabatic processes are often characterized by a change in entropy.

3. What is the relationship between change in entropy and temperature?

The change in entropy of a system is directly proportional to the change in temperature. This means that as the temperature increases, the entropy of the system also increases. Conversely, as the temperature decreases, the entropy decreases as well.

4. How does change in entropy affect the efficiency of a process?

The change in entropy can have a significant impact on the efficiency of a process. In general, an increase in entropy leads to a decrease in efficiency, as more energy is lost in the form of heat. This is why it is important to minimize entropy in order to maximize the efficiency of a process.

5. Can entropy be reversed?

According to the second law of thermodynamics, the total entropy of a closed system will always increase over time. While it is possible to reduce the entropy of a specific system, the overall entropy of the universe will always continue to increase. This is known as the arrow of time and is a fundamental principle in thermodynamics.

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