Change in pressure and Internal Energy

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SUMMARY

The discussion centers on the relationship between pressure changes and internal energy in thermodynamics, specifically for a monatomic ideal gas. The equation ΔU = Q + W is established, with ΔU also expressed as 3/2 nRΔT. The user correctly deduces that for an isovolumetric process, the change in internal energy can be calculated using ΔU = 3/2 ΔP V. A specific example is provided where a pressure change from 200 Pa to 100 Pa and a constant volume of 6 m³ results in a change in internal energy of 900 J. The discussion raises questions about the limitations of using ΔU = 3/2 ΔPV when initial and final PV values are known.

PREREQUISITES
  • Understanding of the first law of thermodynamics (ΔU = Q + W)
  • Familiarity with ideal gas laws (PV = nRT)
  • Knowledge of thermodynamic processes, particularly isovolumetric processes
  • Concept of internal energy and its relation to temperature and pressure changes
NEXT STEPS
  • Study the derivation and applications of the equation ΔU = 3/2 nRΔT for monatomic ideal gases
  • Explore the implications of isovolumetric processes in thermodynamics
  • Investigate the limitations of using ΔU = 3/2 ΔPV in various thermodynamic scenarios
  • Learn about P-V diagrams and how to calculate work done in different thermodynamic processes
USEFUL FOR

Students and professionals in physics and engineering, particularly those studying thermodynamics, heat transfer, and ideal gas behavior.

wongrufus
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I'm aware of the equation
ΔU = Q + W
ΔU is the change in internal energy which equals 3/2 nRΔT
Q is heat transfer
W is workdone

so PV = nRT
would it be correct to say that
ΔP V = nRΔT?

For isovolumetric process (i.e. no volume change, no work done),
can i say that
change in internal energy = 3/2 nRΔT = 3/2 ΔP V?

Say
Pressure changes from 200Pa --> 100Pa
Volume remains at 6 m^3
Would it be right to conclude that the change in internal energy = 3/2 x 100 x 6 = 900J?

**New Question: Is it possible (and if possible, under what condition) that the initial PV and final PV are known BUT the change in internal energy cannot be found directly by ΔU = 3/2 ΔPV?
coz i always come across questions where a P-V graph is given but the internal energy has to be calculated by more complicated methods,
i.e. ΔU = Q + W and not ΔU = 3/2 ΔPV

thx*c
 
Last edited:
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I believe that is correct for a monatomic ideal gas. 900 J of heat flows into the system, which raises the temperature, which increases the pressure, which accounts for the increase in internal energy by the relation ΔU=3/2 ΔP V as you say.
 
does the equation
ΔU = 3/2 nRΔT = 3/2 PΔV = 3/2 ΔPV
have its limitations?
 

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