Charge carrier concentration measurements in working electrode

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shay
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Dear All

I will be grateful for any idea on how to measure electrochemically the charge carrier in an electrode say working electrode made of Al.

Thank you from advance

Shay
 
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I refers to charge carrier concentration.
One way is to measure Mott Schottky plot, however it is model dependent through Impedance.
Is there any other electrochemical method?