Clarification Regarding the conditions for STP

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SUMMARY

The discussion clarifies the definition of Standard Temperature and Pressure (STP) as presented in two chemistry textbooks: Changs and Atkins. Changs defines STP as 25 degrees Celsius and 1 atm, while Atkins uses 25 degrees Celsius and 1 bar. Although both definitions yield nearly identical numerical values, there is no universally accepted standard for STP. The International Union of Pure and Applied Chemistry (IUPAC) recommends using 1 bar as the standard pressure for scientific contexts.

PREREQUISITES
  • Understanding of thermodynamic concepts, specifically STP.
  • Familiarity with pressure units: atmospheres and bars.
  • Knowledge of chemistry textbooks, particularly Changs and Atkins.
  • Basic grasp of IUPAC standards in chemistry.
NEXT STEPS
  • Research the IUPAC recommendations for standard states in chemistry.
  • Explore the historical context of pressure units in scientific literature.
  • Learn about the implications of using different pressure units in chemical calculations.
  • Investigate how STP definitions affect experimental results in chemistry.
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Chemistry students, educators, and professionals who require clarity on the definitions and applications of STP in scientific research and education.

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Hello all,

I am currently in possession of two chemistry textbooks, Changs and Atkins, which I believe are both fairly new versions. Changs defines STP at 25 degrees Celsius and 1 atm, and Atkins defines STP at 25 degrees Celsius and 1 bar; I understand that numerically it would not make a huge difference (1 atm=101.3 kpa=almost 100 kpa), but which is technically correct?

Thanks.
 
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There is no one, universally accepted definition of STP. Bar is a recommended pressure for a standard state.
 
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Atmospheres were used for something like 100 years until "they" decided to switch standard pressure to 1 bar. Numerically they are nearly identical, obviously.

Ref: http://goldbook.iupac.org/S05921.html
(Getting a lot of mileage out of IUPAC today :smile:)
 

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