If you connect two capacitors only, they can be considered either series or parallel. But series capacitors have the same charge, positive on one of the connected plates and negative on the other one. It is not the case now, but you can take the two capacitors connected in parallel. What is the resultant capacitance ?
Both capacitors had 50 V voltage across their plates initially, but the positive plates are connected to the negative ones. You can not add the voltages!The voltage becomes the same on parallel connected elements.
But you can calculate the voltage across the equivalent capacitor using the charge and the resultant capacitance.
The image shows the initial situation, the capacitors charged, then connected, electrons move to neutralize the positive charges and the picture below shows the equivalent capacitor.
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