Degrees of freedom in a reacting system

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In a reacting system, solid CaCO3 and solid CaO are classified as different phases because they do not form a solid solution, despite both being solids. This classification is similar to how oil and water represent two distinct liquid phases. The distinction arises from the fact that each solid has different chemical properties and compositions. Understanding phase behavior is crucial in thermodynamics and reaction kinetics. Therefore, recognizing separate phases is essential for accurate analysis in chemical systems.
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Hello
I am confused in part b why they classify solid CaCO3 and solid CaO as two different phases. They are both solids, which is one phase
 
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Unless they form a solid solution, they represent separate two solid phases. This is analogous to oil and water forming two liquid phases.

Chet
 
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