Derive the van der Waal interaction between 2 spheres.

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The discussion focuses on deriving the van der Waals interaction potential between two spheres using the Hamaker approach, specifically addressing the distance between their centers. Participants seek clarification on the derivation process and references that explain the concept better, highlighting the importance of the pairwise addition assumption in the Hamaker method. A double volume integration of the densities of the spheres is suggested as a starting point for the derivation. Links to relevant papers and equations are provided to aid understanding, with one participant noting the usefulness of Mathematica for calculations. The conversation emphasizes the complexity of the derivation while offering resources for further study.
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Hi guys, I need some help on this question:

Derive the van der Waal interaction potential between 2 spheres of radius R_1 and R_2 using the Hamaker approach. Take the distance between the center of each sphere to be D.

Thank you very much for your help!
 
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Read this:

http://dept.lamar.edu/chemicalengineering/www/tadmor/papers/vanderwaalsforces/vdw1.pdf

Could you explain me a little bit more about that?
Or some reference?
I know nothing about it.

Is the van der Waal interaction a starting point, or is it a consequence?
Is there a short (fast) derivation for formula (1) somewhere available?

Interresting because of the geeko.
 
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The Hamaker approach assume a pairwise addition, so the derivation start with a double volume integration of density_1 and density_2 and c over r^6, where r is the separation between the small volume in the integration, and c is a constant. Not sure if I make myself clear here.

Maybe this pdf will help, please refer to page 2, equation (1) for the mathematical description of what I had describe above. Thanks! Here is the link: http://chemeng.queensu.ca/courses/CHEE460/lectures/documents/CHEE4602010Lecture4.pdf

And yes the gecko is a master of VDW forces!
 
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I don't know if it is helpfull, but here is a link to the original paper by Hamaker:

http://www.utwente.nl/tnw/pcf/education/jmbc_course_on_capillarity_driv/Articles/anton_darhuber/surface_tension_etc/Hamaker_Physica1937_vdW_attract_spherical_particles.pdf

It is a little bit lengthy and even boring.
It looks like it is only about calculating the integral of formula (1) in the paper.
Probably a piece of cake if you have 1 hour free and Mathematica.

Thanks for the reference: it is very clear and readable.
 
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Thank you for your help. Mathematica does help.
 
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