Determining Initial and Equilibrium Concentration (Help )

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Discussion Overview

The discussion revolves around calculating initial and equilibrium concentrations in a chemical reaction involving Fe3+ and SCN- ions. Participants are focused on a specific homework problem related to the preparation of a solution and the subsequent calculations required for determining concentrations.

Discussion Character

  • Homework-related

Main Points Raised

  • One participant presents a homework problem involving the reaction Fe3+ + SCN- -> FeSCN- and provides specific data for calculations.
  • Another participant seeks clarification on the dilution process of SCN- and how to calculate its concentration in the final solution.
  • There is a discussion about whether the presence of NaSCN affects the calculations, with one participant asserting that it does not matter for the concentration of SCN-.
  • Participants confirm that the concentration of SCN- remains the same regardless of the sodium ion's presence in the solution.

Areas of Agreement / Disagreement

Participants generally agree that the concentration of SCN- can be treated the same regardless of it being in the form of NaSCN. However, there is some uncertainty about the relevance of certain details in the context of the problem.

Contextual Notes

Participants have not fully explored the implications of assuming all SCN- is present as FeNCS2+, and there may be additional considerations regarding the calculations that remain unaddressed.

Who May Find This Useful

Students working on similar chemistry problems involving equilibrium concentrations and dilution calculations may find this discussion helpful.

galaticman
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Determining Initial and Equilibrium Concentration (Help!)

Homework Statement


You are given the equation Fe3+ + SCN- -> FeSCN-
You are performing an experiment in which you are mixing Fe(NO3)3 and NaSCN. A table is given and I will only list the first sets of data because if i can figure out the process for the first one I can figure out the rest. The table is:

10 mL of 2.0x10-3 M Fe(NO3)3
2mL of 2.0x10-3
Total Volume of Solution: 50mL

You are asked to to calculate the initial SCN- concentration (M) as well as the equilibrium FeNCS2+ concentration (M)

I am just not sure how to go about doing that. Any help would be greatly appreciated!

NOTE: It also mentions that to assume all of the SCN- is present as FeNCS2+ but I am pretty sure that this is irrelevant and is relevant to the later part of the lab
 
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So, if I understand you correctly, you take 2 mL of 2x10-3M solution of SCN-, and you dilute it up to 50 mL (other solution doesn't matter at this moment)?

How many moles of SCN- in these 2 mL? What is the concentration of the solution containing this amount of SCN- in a 50 mL volume?
 


Yup that is pretty much it except it is not just SCN it is NaSCN but I am not sure if that matters for the problem or not?
 


It doesn't matter - if the solution is 2x10-3 M in NaSCN, it is also 2x10-3 M in Na+ and SCN-.
 


Ohhhh okay I got it then! Thanks!
 

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