Direction of vibration of molecule with respect to transfer of heat

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Heat causes molecules to vibrate, but the direction of this vibration can differ from the direction of heat transfer in conduction, convection, and radiation. In metallic conduction, the movement of electrons plays a more significant role in heat transfer than molecular vibrations. While individual molecules may vibrate in various directions, the overall net movement aligns with the direction of heat transfer. It's important to note that heat transfer occurs in three dimensions at the molecular level. Understanding these dynamics is crucial for comprehending heat transfer mechanisms.
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the heat causes the molecule to vibrate.how does the molecule vibrate in terms of angle formed by vibrating molecule and the direction of tranfer of heat in conduction, convention and radiation?
 
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That would be really difficult to answer at individual molecule/atom level for conduction. If you are looking at conduction in metals, you should be worried more about movement of electrons which forms a major part of heat transfer and molecular vibration only a little. Having said that, the individual molecules may vibrate in directions other than the direction of heat transfer but the net movement will be in the direction of heat transfer (remember heat transfer is never in one direction - it is always 3 dimensional when you are looking at molecular level)
 
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