Distilling Ethanol by Refrigerating

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Ethanol is gaining traction as an alternative fuel for vehicles. A proposed method for distilling ethanol involves cooling a mixture to below the freezing point of water, allowing the ethanol, which has a lower density than water, to float to the top for separation. This method is reminiscent of traditional beer-making techniques in Germany, where brewers would freeze kegs of lager to concentrate alcohol. While this cooling method can work to some extent, it has limitations; the purity of ethanol cannot be maximized beyond a certain point due to the remaining water content, similar to how 80 proof vodka does not freeze in a freezer. For higher purity, conventional distillation methods should be employed after initial cooling.
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Ethanol seems to be popular for an alternative fuel for cars. If you distilled the ethanol by cooling it and exceeding the saturation point, because it has a lower density than water (.789 grams/cubic cm), the ethanol it would float to the top. You could take the mixture below the freezing point of water and poor the ethanol off the top. My question is, could this work as a distillation method, or am I just wrong?
 
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i believe this is actually how high alcohol-containing beers were first made in germany..they would take two kegs of lager, leave them outside to be frozen, then take the part that didnt freeze (ethanol + other stuff) and combine that with a fresh keg of lager. (nowadays most places use new strains of yeast or just add pure ethanol).
 
drosser said:
Ethanol seems to be popular for an alternative fuel for cars. If you distilled the ethanol by cooling it and exceeding the saturation point, because it has a lower density than water (.789 grams/cubic cm), the ethanol it would float to the top. You could take the mixture below the freezing point of water and poor the ethanol off the top. My question is, could this work as a distillation method, or am I just wrong?

yes it works, but you are only going to be able to get the ethanol pure to a certain amount before the water will stop freezing out--just take like how a bottle of 80 proof vodka won't freeze if you put it in the freezer.
 
gravenewworld said:
yes it works, but you are only going to be able to get the ethanol pure to a certain amount before the water will stop freezing out--just take like how a bottle of 80 proof vodka won't freeze if you put it in the freezer.

distill it in the regular fashion after that
 
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