Gauss' Law can be used to find the electric field from a charge distribution, but it is most effective when symmetry is present. For symmetrical cases, such as a point charge or uniformly charged sphere, the electric field can be derived directly from the law by considering the electric flux through a Gaussian surface. However, when symmetry is absent, Gauss' Law does not provide enough information to uniquely determine the electric field at a point. In such scenarios, the electric field may be zero, but this does not imply the absence of charges elsewhere; for example, the electric field inside a uniformly charged shell is zero despite the presence of charge on the shell's surface. Understanding the limitations of Gauss' Law is crucial for accurately applying it to different charge configurations.