To determine the charge of a suspended Styrofoam ball under an electric field, one must consider the forces acting on it, specifically gravity and the electric force. The electric field direction indicates the sign of the charge; if the electric field points down and opposes gravity, the charge must be negative. A free body diagram can help visualize these forces, leading to the application of static equilibrium principles. By relating electric field and electric force, one can derive an equation to solve for the charge in terms of the electric field. Knowing the electric field value allows for a numerical solution for the charge.