ELectrochemical sensing problem

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The discussion centers on deriving Fick's law of diffusion in the context of electrochemical sensing. It highlights the relationship between current density and various parameters, including flux, number of electrons, Faraday constant, particle speed, charge carriers, cross-sectional area, and electron charge. Participants seek guidance on starting the derivation and understanding the underlying principles. Links to external resources are provided for further exploration of the topic. The conversation emphasizes the need for clarity in applying Fick's law to electrochemical systems.
vinke
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Anyone knows how to derive Fick's law of diffusion:

I=Jmf

Given current density applied to electrochemical sensing:
I= nAve

where :
I=current
J=flux
m=number of electrons
F=faraday constant
v=speed of particles
n=number of charge carriers/vol
A= cross-sectional area of sensor(electrode)
e=charge of an electron


Please help, at least give a clue where to start and the procedings.
Thanx
 
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Peruse through these...

http://www.smecc.org/r.m.r_fick's_law.htm

http://www.webcom.com/rphair/bis/resources/cybertext/chapter7.html
 
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