Rocky Raccoon said:
What's the most persuasive argument for using the potential phi and A as independent deegres of freedom in the electromagnetic Lagrangian instead of the more physical field E and B? Why does the cannonical approach break down for E and B?
Every theory that is based on a least action principle that I know of assumes that the Lagrangian depends on at most, first derivatives of the field. When we perform a variation, we get equations that involve second derivatives of the field. Maxwell's equations involve only first derivatives with respect to the electric and magnetic fields. Keeping in mind that the electromagnetic fields are expressed as first derivatives of the electromagnetic potentials, it means that maxwell's equations are second order equations with respect to the potentials. Then, one can formulate a Lagrangian which gives an action, which, upon varying with respect to the the potentials, not the fields, gives the proper Maxwell's equations.
Then, if you write the Lorentz force acting on a point charge in terms of the potentials:
<br />
\mathbf{F} = q \left[-\frac{1}{c} \frac{\partial \mathbf{A}}{\partial t} - \nabla \Phi + \frac{1}{c} (\mathbf{v} \times (\nabla \times \mathbf{A}))\right]<br />
Then, using the double crossed product formula:
<br />
(\mathbf{v} \times (\nabla \times \mathbf{A})) = \nabla(\mathbf{v} \cdot \stackrel{\downarrow}{\mathbf{A}}) - (\mathbf{v} \cdot \nabla) \mathbf{A} = \nabla(\mathbf{v} \cdot \mathbf{A}) - (\mathbf{v} \cdot \nabla) \mathbf{A}<br />
and the fact that the total time derivative:
<br />
\frac{d \mathbf{A}}{d t} = \frac{\partial \mathbf{A}}{\partial t} + (\mathbf{v} \cdot \nabla) \mathbf{A}<br />
we can write the Lorentz force as:
<br />
\mathbf{F} = \frac{d}{d t}\left(-\frac{q}{c} \mathbf{A}\right) - \nabla\left[q \left(\Phi - \frac{1}{c} (\mathbf{v} \cdot \mathbf{A})\right)\right]<br />
Then, if we introduce a
generalized potential:
<br />
U = q \left[\Phi - \frac{1}{c}(\mathbf{v} \cdot \mathbf{A})\right]<br />
we can write the Lorentz force as:
<br />
\mathbf{F} = \frac{d}{d t} \frac{\partial U}{\partial \mathbf{v}} - \nabla U<br />
So, the force is expressible through a potential of the form as the Lagrange's equations. This potential enters in the Lagrange function for the particle in an external electromagnetic field. As you can see, this potential energy is expressible in terms of the electromagnetic potentials.
Finally, according to QFT, the electromagnetic potentials form a 4-vector of a gauge field of the local U(1) symmetry.