Entropically or Enthelpically favorable?

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In summary, "entropically or enthalpically favorable" refers to processes or reactions with a negative change in entropy or enthalpy, making them more likely to occur spontaneously. Entropy and enthalpy are related thermodynamic properties, with entropy representing disorder and enthalpy representing total energy. A process or reaction can be entropically and enthalpically favorable, and scientists use these concepts in their research to understand and predict the behavior of systems and reactions.
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metalmagik
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Homework Statement


6CO2 + 6 H2O → C6H12O6 + 6 O2



Homework Equations





The Attempt at a Solution


I believe that this is entropically and enthalpically unfavorable because the reaction is going to more order (synthesis of glucose) and heat is not being generated.

Is my logic correct? Thanks anyone for any help you can give me.
 
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  • #2
Somewhat ... you've got more molar gas on the left , in addition this is a reverse combustion reaction , you should know that it is combustion reactions that are exothermic.
 
  • #3


Your logic is partially correct. The synthesis of glucose does indeed increase order (and therefore decrease entropy) in the system. However, the overall reaction is still entropically favorable because the production of 6 molecules of O2 results in a significant increase in entropy. Additionally, the enthalpy change for this reaction is negative, meaning it is exothermic and releases heat. Therefore, while the synthesis of glucose may be enthalpically unfavorable, the overall entropy and enthalpy changes make this reaction favorable.
 

1. What is meant by "entropically or enthalpically favorable"?

When a process or reaction is described as "entropically or enthalpically favorable", it means that the change in entropy or enthalpy, respectively, is negative. In other words, the process or reaction is more likely to occur spontaneously because it results in a decrease in disorder (entropy) or an increase in energy (enthalpy).

2. How are entropy and enthalpy related to each other?

Entropy and enthalpy are both thermodynamic properties that describe the state of a system. Entropy is a measure of the disorder or randomness of a system, while enthalpy is a measure of the total energy of a system. These two properties are related by the equation ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature, and ΔS is the change in entropy.

3. What makes a process or reaction entropically or enthalpically favorable?

A process or reaction is entropically or enthalpically favorable when the change in entropy or enthalpy is negative. This can happen in a variety of ways, such as an increase in temperature, a decrease in volume, or the formation of more stable products. Essentially, any change that results in a decrease in disorder or an increase in energy will make a process or reaction more favorable.

4. Can a process or reaction be both entropically and enthalpically favorable?

Yes, it is possible for a process or reaction to be both entropically and enthalpically favorable. This means that the change in both entropy and enthalpy is negative, indicating that the process or reaction is highly likely to occur spontaneously. An example of this is the dissolution of salt in water, which is both entropically and enthalpically favorable.

5. How do scientists use the concepts of entropy and enthalpy in their research?

Scientists use the concepts of entropy and enthalpy in a variety of ways, particularly in the fields of thermodynamics and chemistry. These properties are important for understanding the behavior of systems and reactions, and can help predict the outcome of experiments. For example, knowledge of enthalpy and entropy can be used to optimize reaction conditions, design more efficient processes, and develop new materials with specific properties.

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