Entropy change of ice-water mixture at 273K

AI Thread Summary
The discussion focuses on calculating the entropy change of a system consisting of a mixture of water and ice at 273K. The initial state has 1.773kg of water and 227g of ice, transitioning to a final state with a 1:1 mass ratio of ice to water. The calculations involve determining the mass of water that freezes and the corresponding energy change using the specific heat of fusion. The initial attempt yielded an entropy change of -912 J/K, but it was corrected to -915 J/K by using the accurate heat of fusion value of 334 J/g. The conversation emphasizes the importance of precise values in thermodynamic calculations.
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Homework Statement


A mixture of 1.773kg of water and 227g of ice is in an initial equilibrium state at 273K, in a reversible process, brought to a second equilibrium state where the water-ice ratio,by mass, is 1:1 at 273K. Calculate the entropy change of the system during the process.

Homework Equations


E=mL
\Delta S=\int\limits_{i}^{f}\frac{dQ}{T}
specific heat of fusion of water = 333000J/kgK

The Attempt at a Solution



Since final mass ratio is 1:1 the final mass is both ice and water is
m=(1.733+0.277)/2=1.025kg, which means 0.748 kg of water is turned to ice. Some water gives away energy and freezes to ice.
\Delta E=-0.748(333000)=-249084J
\Delta S=-249084/273=-912J/K
But that is not the answer.
 
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lowerlowerhk said:
Since final mass ratio is 1:1 the final mass is both ice and water is
m=(1.773+0.277)/2=1.025kg, which means 0.748 kg of water is turned to ice. Some water gives away energy and freezes to ice.
\Delta E=-0.748(333000)=-249084J
\Delta S=-249084/273=-912J/K
But that is not the answer.
Your method is correct. Use 334 J/g as the heat of fusion for water. I get -915 J/K

AM
 
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