Equilibrium Constant Table Method

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Discussion Overview

The discussion revolves around understanding the equilibrium constant table method, specifically focusing on how to interpret changes in moles of reactants and products in a chemical reaction. Participants explore the relationships between initial quantities, changes, and equilibrium quantities in the context of a reaction involving ammonia (NH3), nitrogen (N2), and hydrogen (H2).

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Homework-related

Main Points Raised

  • One participant expresses confusion about the "Change (mol)" in the equilibrium table and seeks clarification.
  • Another participant suggests using molar ratios to determine how many moles of N2 and H2 are needed to produce 1 mole of NH3.
  • A participant explains that to produce 2 molecules of NH3, 1 molecule of N2 is required, leading to the conclusion that 1/2 mole of N2 is needed for 1 mole of NH3.
  • There is a discussion about how to calculate the change in moles, with one participant confirming that the mole ratios for N2 and H2 relative to NH3 are 0.5 and 1.5, respectively, and noting that the signs are negative for reactants being consumed.
  • A question is raised about the implications of a negative change for NH3, suggesting that it would indicate a reverse reaction, with reactants increasing.
  • Another participant agrees that initial NH3 would be necessary for the reverse reaction to occur.

Areas of Agreement / Disagreement

Participants generally agree on the relationships between moles of reactants and products, but there is some uncertainty regarding the implications of negative changes and the conditions required for reverse reactions.

Contextual Notes

The discussion does not resolve the broader implications of changes in equilibrium or the specific conditions under which reactions may reverse, leaving these aspects open for further exploration.

TheRedDevil18
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Hi, I just want someone to explain this table to me please, I am totally confused especially with the Change(mol).
Question below:

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If 1 Mole of NH3 is produced, how many moles of N2 and H2 were used to do that?
Hint: Use the molar ratio.

If you know the initial quantity and the change, you get the quantity at equilibrium.
 
How?, still a bit confused. Could you show me?
 
Is "how" related to the quantity at equilibrium?
This is a simple addition. If you start with X moles and produce Y moles, you have X+Y moles.

Is "how" related to the other part?
Just keep in mind that the total number of atoms (both for N and H) cannot change.
 
I mean the Change, how do they get the change?
 
To produce 2 molecules of NH3, you need 1 molecule of N2 (to have 2 N atoms).
To produce 1 molecule of NH3, you need 1/2 molecule of N2.
To produce 1 mole of NH3 (this is given), you need 1/2 moles of N2.

It is that easy.
 
Okay I understand it now, mole ratio N2:NH3 1/2*1=0.5 and H2:NH3 3/2*1=1.5, the signs are negative because they are being used up right?
 
What would happen if the change is negative for NH3, Would it now mean that NH3 is being reversed back into its reactants and the reactants would be positive?
 
  • #10
You would need some initial NH3 for that.
In that case: Right.
 
  • #11
Okay I think that's it, Thanks for your help
 

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