We wish to place a small charged sphere at a distance of 5.0 m from a point in space such that the voltage at that point is 1.20 V. How much charge should be on the sphere (in nC)?
That second equation you're using with the r^2, don't use that one. The one you want to use is the first one. k is a constant and r is the radial distance (the question specifies that as 5.0m). If the voltage at that point is 1.20V, and you know the value of k and r, then just solve for Q.