The method of undetermined coefficients is just where you have undetermined coefficients and you determine them. It is a general idea. You can apply it to ODEs, but say you have a 2x2 matrix. Say you want to find its inverse. Multiply it by some general matrix with undetermined coefficients, and you'll get a bunch of linear equations for which you can solve for the undetermined coefficients and thereby find the inverse (if your original matrix was invertible). Suppose you have a power series f(x) and you want to find a power series g(x) such that f(x)g(x) = 1. Then you would do this by undetermined coefficients, i.e. g(x) is a power series with undetermined coefficients, then you can express f(x)g(x) as a power series with coefficients in terms of those of f and those of g, giving you a bunch of equations in which you can solve the undetermined coefficients.
Anyways, is Zp[x] even a field. I haven't studied much of this, but are you sure that elements have inverses? Suppose you have some polynomial q(x) of degree deg(q) with leading ceofficient aq. It's inverse would be some polynomial r(x) of degree deg(r) with leading coefficient ar. The product q(x)r(x) should be 1, so the coefficient of xdeg(q)+deg(r) ought to be 0, but it will be aqar which cannot be 0 if p is prime.
If this is right, then only polynomials of degree 0 have inverses. Or am I way off? Maybe I even have the multiplication wrong. When I've studied polynomial rings, the multiplication of polynomials has been p(x)q(x), but maybe you're studying something different where multiplication is composition, i.e. p(q(x)). In this case identity would be x, not 1, and the question of finding inverses gets more complicated, I think.