From Hot to Cool: A Change in Entropy

AI Thread Summary
The discussion revolves around calculating the net change in entropy (Delta Ssys) when mixing 1.0 kg of water at 20°C with 1.0 g of ice at 0°C in a well-insulated calorimeter. The heat of fusion for ice is provided, and the assumption is that the temperature remains constant during the melting process. Initial calculations for Delta Sice and Delta Swater were presented, but the user sought verification of their results. After some back-and-forth, it was confirmed that the correct net change in entropy is 0.084 J/K, correcting earlier miscalculations. The conversation highlights the importance of accurate input values in thermodynamic calculations.
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Homework Statement


In a well-insulated calorimeter, 1.0 kg of water at 20o C is mixed with 1.0 g of ice at 0o C.

What is the net change in entropy Delta Ssys of the system from the time of mixing until the moment the ice completely melts? The heat of fusion of ice is Lf=3.34x105 J/kg.
Note that since the amount of ice is relatively small, the temperature of the water remains nearly constant throughout the process. Note also that the ice starts out at the melting point, and you are asked about the change in entropy by the time it just melts. In other words, you can assume that the temperature of the "ice water" remains constant as well.

Homework Equations


Ssys = Sice+Swater
Delta Sice = Qice/T
Qwater = -Qice (amount of heat lost to the ice)
Delta Swater = -Qice/T

The Attempt at a Solution


Delta Sice = (0.001 kg * 3.34x105 J/kg)/(0+273) = 1.22
Delta Swater = -334/(20+273) = -1.14
Delta S sys = 996.59

I think that this could be the correct answer, however, I would just like verification that it is correct. I have gotten the answer 1200, which seems to be a popular answer amongst my classmates, and it was not correct.
 
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I don't know about your numbers, but your approach looks good. Oh, it looks like you made a mistake inputting the value for Q_water.
 
Thank you for point it out! I found the correct answer of 0.084 J/K.
 
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