Hartree-Fock Method vs. Configuration Interaction

filippo
Messages
10
Reaction score
0
I am trying to find a clear description of what makes the convergence of the error in electronic energy with respect to orbital basis set less rapid in CI calculations than in HF calculations.

Can anyone help to find the reason?
 
Physics news on Phys.org
I think the CI calculation is just generally more complicated since it can account for correlation and whatnot.
 
Insights auto threads is broken atm, so I'm manually creating these for new Insight articles. Towards the end of the first lecture for the Qiskit Global Summer School 2025, Foundations of Quantum Mechanics, Olivia Lanes (Global Lead, Content and Education IBM) stated... Source: https://www.physicsforums.com/insights/quantum-entanglement-is-a-kinematic-fact-not-a-dynamical-effect/ by @RUTA
If we release an electron around a positively charged sphere, the initial state of electron is a linear combination of Hydrogen-like states. According to quantum mechanics, evolution of time would not change this initial state because the potential is time independent. However, classically we expect the electron to collide with the sphere. So, it seems that the quantum and classics predict different behaviours!
Back
Top