Help with Quantum Mechanics and Continuity Equation

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Homework Help Overview

The discussion revolves around the properties of a Bose-Einstein condensate described by a wave function, specifically focusing on the probability density, probability current density, and the continuity equation. The subject area is quantum mechanics, particularly the mathematical formulation of wave functions and their implications in physical systems.

Discussion Character

  • Exploratory, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the calculation of probability density and current density, with some attempting to derive the continuity equation based on these results. Questions arise regarding algebraic errors and the interpretation of derivatives in the context of the continuity equation.

Discussion Status

Some participants have identified potential errors in calculations and are revising their approaches. There is ongoing clarification about the relationship between different terms in the continuity equation and the implications of the wave function's form. The discussion is productive, with participants actively engaging in correcting misunderstandings and refining their reasoning.

Contextual Notes

Participants note the complexity of the problem due to the need for careful differentiation and the application of product and chain rules in the context of quantum mechanics. There is an acknowledgment of the challenge posed by the abstract nature of the functions involved.

  • #31
Okay so:

i\hbar\left(\rho i \frac{\partial \phi}{\partial t} + \frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(i\phi&#039;i \phi&#039; + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho\rho&#039;\rho&#039;2\rho - \rho\rho&#039;^2}{4\rho} \right) + \frac{\rho\rho&#039;}{2} i\phi\rho&#039;\right) + V\rho <br />

Okay so far?
 
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  • #32
On the third term on the rhs you got an extra rho which wasn't there in your previous steps. Also you can multiply the i s in the first term of the rhs to get -1.
 
  • #33
Okay,

i\hbar\left(\rho i \frac{\partial \phi}{\partial t} + \frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(i\phi&#039;i \phi&#039; + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho&#039;\rho&#039;2\rho - \rho\rho&#039;^2}{4\rho} \right) + \frac{\rho\rho&#039;}{2} i\phi\rho&#039;\right) + V\rho

and:

hbar\left(-\rho \frac{\partial \phi}{\partial t} + i\frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} \right) + \frac{\rho\rho&#039;}{2} i\phi\rho&#039;\right) + V\rho

Does this look better?
 
  • #34
No, it looks to me that the fourth term on the rhs has one extra rho and one extra rho prime, while the prime on phi has disappeared.
 
  • #35
Okay:

hbar\left(-\rho \frac{\partial \phi}{\partial t} + i\frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho&#039; 2\rho - \rho&#039;^2}{4\rho} \right) + \frac{\rho\rho&#039;}{2} i\phi&#039;\rho&#039;\right) + V\rho

Better?
 
  • #36
no, the fourth term, not the third one.
 
  • #37
hbar\left(-\rho \frac{\partial \phi}{\partial t} + i\frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} \right) + \frac{1}{2} i\phi&#039;\rho&#039;\right) + V\rho <br />

?
 
  • #38
perfectly alright !
 
  • #39
Okay so:

\hbar\left(-\rho \frac{\partial \phi}{\partial t} + i\frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} \right) + \frac{1}{2} i\phi&#039;\rho&#039;\right) + V\rho

Okay, so what should I do now?
 
  • #40
What does the question ask you to do?
 
  • #41
Well, it asks you to split the function up into imaginary and real parts. Have we sorted this out enough to do this now?
 
  • #42
Yup. Go ahead and split it.
 
  • #43
Okay, so:

\hbar\left(-\rho \frac{\partial \phi}{\partial t} + i\frac{1}{2}\frac{\partial \rho}{\partial t}\right) = \frac{\hbar^2}{2m} \left(\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{i\phi&#039;\rho&#039;}{2} + \left( \frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} \right) + \frac{1}{2} i\phi&#039;\rho&#039;\right) + V\rho

Multiply out brackets:

-\hbar\rho \frac{\partial \phi}{\partial t} + \hbar i\frac{1}{2}\frac{\partial \rho}{\partial t} =<br /> \frac{\hbar^2}{2m}\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{\hbar^2}{2m}\frac{i\phi&#039;\rho&#039;}{2} + \frac{\hbar^2}{2m}\frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} + \frac{\hbar^2}{2m}\frac{1}{2} i\phi&#039;\rho&#039; + V\rho

So should I just out the parts with an i on one side, and the real parts on the other side of the equals sign (ie i f(x) = g(x))?
 
  • #44
No. If you have a complex equation of the form

f+ ig = p +is where f,g,p,s are real, it follows that f=p and g=s. Here you have to equate the coefficients of the number i on both sides.
 
  • #45
Okay, so:

-\hbar\rho \frac{\partial \phi}{\partial t} + \hbar i\frac{1}{2}\frac{\partial \rho}{\partial t} = \frac{\hbar^2}{2m}\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{\hbar^2}{2m}\frac{i\phi&#039;\rho&#039;}{2} + \frac{\hbar^2}{2m}\frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} + \frac{\hbar^2}{2m}\frac{1}{2} i\phi&#039;\rho&#039; + V\rho

So if we start on the left side:

-\hbar\rho \frac{\partial \phi}{\partial t} + \hbar i\frac{1}{2}\frac{\partial \rho}{\partial t}

We have:

-\hbar\rho \frac{\partial \phi}{\partial t} + i\left(\frac{\hbar}{2}\frac{\partial \rho}{\partial t}\right)

Does this look okay?
 
  • #46
Yes. go on.
 
  • #47
Okay, now for the right side:

\frac{\hbar^2}{2m}\rho(-\phi&#039;^2 + i\phi&#039;&#039;) + \frac{\hbar^2}{2m}\frac{i\phi&#039;\rho&#039;}{2} + \frac{\hbar^2}{2m}\frac{\rho&#039;^22\rho - \rho\rho&#039;^2}{4\rho} + \frac{\hbar^2}{2m}\frac{1}{2} i\phi&#039;\rho&#039; + V\rho

-\frac{\hbar^2\rho\phi&#039;^2 }{2m} + \frac{\hbar^2\rho i\phi&#039;&#039;}{2m} + \frac{i\phi&#039;\rho&#039;\hbar^2}{4m} + \frac{\hbar^2\rho&#039;^22\rho - \hbar^2\rho\rho&#039;^2}{8m\rho} + \frac{\hbar^2 i\phi&#039;\rho&#039; }{4m}+ V\rho

Thus:

-\frac{\hbar^2\rho\phi&#039;^2 }{2m} +\frac{\hbar^2\rho&#039;^22\rho - \hbar^2\rho\rho&#039;^2}{8m\rho}+ V\rho + \frac{\hbar^2\rho i\phi&#039;&#039;}{2m} + \frac{i\phi&#039;\rho&#039;\hbar^2}{4m} + \frac{\hbar^2 i\phi&#039;\rho&#039; }{4m}


-\frac{\hbar^2\rho\phi&#039;^2 }{2m} +\frac{\hbar^2\rho&#039;^22\rho - \hbar^2\rho\rho&#039;^2}{8m\rho}+ V\rho + i\left(\frac{\hbar^2\rho \phi&#039;&#039;}{2m} + \frac{\phi&#039;\rho&#039;\hbar^2}{4m} + \frac{\hbar^2 \phi&#039;\rho&#039; }{4m} \right)

Does this look okay?
 
  • #48
Absolutely okay. Go on, you're almost there.
 
  • #49
So now I have to take the imaginary part. Would that be:

i\left(\frac{\hbar}{2}\frac{\partial \rho}{\partial t}\right) = i\left(\frac{\hbar^2\rho \phi&#039;&#039;}{2m} + \frac{\phi&#039;&#039;\rho&#039;&#039;\hbar^2}{4m} + \frac{\hbar^2 \phi&#039;&#039;\rho&#039;&#039;}{4m} \right)
 
  • #50
Quite correct.
 
  • #51
So now I need to compare this:

i\left(\frac{\hbar}{2}\frac{\partial \rho}{\partial t}\right) = i\left(\frac{\hbar^2\rho \phi&#039;&#039;}{2m} + \frac{\phi&#039;\rho&#039;&#039;\hbar^2}{4m} + \frac{\hbar^2 \phi&#039;&#039;\rho&#039;&#039;}{4m} \right)

to:

-\frac{\partial}{\partial t}\rho(x,t) = \frac{\hbar}{m}\rho(x,t)\phi&#039;&#039;(x,t) + \frac{\hbar}{m}\rho&#039;(x,t)\phi&#039;(x,t)

Well is we

\frac{\partial \rho}{\partial t} = \frac{\hbar\rho \phi&#039;&#039;}{m} + \frac{\phi&#039;\rho&#039;&#039;\hbar}{2m} + \frac{\hbar \phi&#039;&#039;\rho&#039;&#039;}{2m}

They don't seem to similar...?
 
  • #52
Oh. Your previous expression was actually incorrect. The last 2 terms in the rhs should have contained single derivatives of both rho and phi, and not double derivativs (compare with the expression prior to that).
 
  • #53
\frac{\partial \rho}{\partial t} = \frac{\hbar\rho \phi&#039;&#039;}{m} + \frac{\phi&#039;\rho&#039;\hbar}{2m} + \frac{\hbar \phi&#039;\rho&#039;}{2m}

so,

\frac{\partial \rho}{\partial t} = \frac{\hbar\rho \phi&#039;&#039;}{m} + \frac{\phi&#039;\rho&#039;\hbar}{m}

Now this does look more similar...
 

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