High energy rechargeable Aluminum batteries

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SUMMARY

The discussion centers on the potential of high energy density rechargeable aluminum-based batteries, specifically those utilizing aluminum in reactions with metals like iron and oxygen. The key reaction presented is 2Al + Fe2O3 → Al2O3 + Fe, raising questions about the rechargeability of such batteries. Participants express skepticism regarding the rechargeability of aluminum oxide (Al2O3) due to its stability and the challenges in reversing the reaction. The conversation highlights the need for further exploration into the conditions that define battery rechargeability, particularly in relation to aluminum's interactions with other metals.

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  • Understanding of electrochemical reactions and battery chemistry
  • Familiarity with aluminum-based battery technologies
  • Knowledge of metal oxides and their stability
  • Basic principles of electroplating and ion behavior
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  • Research the electrochemical properties of aluminum and its alloys
  • Investigate the mechanisms of aluminum-ion battery technology
  • Explore the stability and decomposition of aluminum oxide (Al2O3)
  • Examine the principles of rechargeability in various battery chemistries
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Stanley514
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In this article http://www.adlabs.com/library/battery.html" (read PDF) an author proposes high energy density rechargeable aluminum-based batteries.They are based on reaction of Aluminum with Iron (or other metals) and oxygen.I still trying to understand why autor is so sure that such type of batteries going to be rechargeable and what is sense to use some other metal (such as Iron) in reaction.
For example: 2Al+Fe2O3 »» Al2O3+Fe2. Is it going to be rechargeable?If yes, why than
Al-air primary battery is non-rechargeable?
 
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Reaction is not different from the one used in termite, two metals are present to make use of their different affinity to oxygen.

No idea about rechargeability, but I have not read the paper. In general Al2O3 is very stable, so difficult to decompose.
 
What aluminum-based batteries supposed to be rechargeable?
For example Aluminum-Iodine is rechargeable?
With what metals aluminum could react reversibly?
 
In general Al2O3 is very stable, so difficult to decompose.
What defines rechargebility of battery?For example if Al2O3 whould be soluble in water
or some other liquid,does it mean it would be rechargeable?
 
No Anion and Cations require differing potentials to be soluble and recoverable , Ie: see Electroplating.
 

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