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Homework Statement
An electron is inside a magnetic field oriented in the z-direction. No measurement of the electron has been made. A magnetic field in the x-direction is now switched on. Calculate the first-order change in the energy levels as a result of this perturbation.
The Attempt at a Solution
I got this wrong, claiming that the first order perturbation is zero. I said this because if you evaluate the expectation of the S_x matrix in the states up/down individually, you obviously get zero since S_x is anti-diagonal.
Apparently you are supposed to evaluate the expectation of S_x in the superposition of states \psi = 1/\sqrt{2}(1,0)^T + 1/\sqrt{2}(0,1)^T. I have trouble understanding this because \psi is not an eigenstate of the orginial Hamiltonian, which it should be for canonical perturbation theory.
Any help is greatly appreciated.