How Does Isothermal Expansion Affect Work and Entropy in an Ideal Gas?

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In an isothermal expansion of an ideal gas at standard temperature and pressure (STP), the work done can be calculated using the formula W = nRTln(V2/V1). For 1 mole of gas at STP, the initial volume is 22.4L, and the temperature is 273.15K. However, without knowing the final volume (V2), the work done cannot be determined. The change in entropy is correctly calculated using the formula ΔS = nRln(V2/V1), resulting in a value of 3.7 J/K for the entropy change. The discussion emphasizes the importance of knowing both the initial and final volumes to accurately compute the work done during the isothermal process.
Dx
Hiya!
A container of ideal gas at STP undergoes an isothermal expansion and its entrop changes by 3.7JdegreeK. How much work does it do?

i have [del]S = [del]S_s + [del]S_env >= 0.

I am confused 1 mol of iseal gas at STP has vol = 22.4L but i usaully given themass also to find Q unless its 37. / 22.4 which gives me 1.0 x 10^3 J.
is this correct?
Thanks!
Dx :wink:
 
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remember isothermal so [del]U = 0

dS = dQ/T

enough there to get the answer.
 


Hi there!

To calculate the work done in an isothermal expansion, we can use the formula W = nRTln(V2/V1), where n is the number of moles of gas, R is the gas constant, T is the temperature in Kelvin, and V2 and V1 are the final and initial volumes, respectively. Since the gas is at STP, we know that the temperature is 273.15K and the initial volume is 22.4L for 1 mol of gas. However, we do not have enough information to calculate the final volume, so we cannot determine the work done. We would need to know the final volume or pressure in order to calculate the work done.

As for the entropy change, your calculation seems to be correct. The change in entropy is given by [delta]S = nRln(V2/V1), where n is the number of moles of gas, R is the gas constant, and V2 and V1 are the final and initial volumes, respectively. Using the values for STP, we get [delta]S = 1 mol x 8.314 J/mol K x ln(V2/22.4L) = 3.7 J/K.

I hope this helps clarify things for you! Let me know if you have any other questions. :)
 
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