How refrigerators and air conditioners work

AI Thread Summary
Refrigerators and air conditioners operate based on thermodynamic principles, utilizing an expansion valve to facilitate the phase change of refrigerants like freon or ammonia. As the liquid refrigerant passes through the evaporator, it absorbs heat from its surroundings, causing it to evaporate into a gas while cooling the interior space. The gas expands, doing work and lowering its internal energy, but it does not solidify because the temperatures involved do not reach the freezing point of the refrigerant. Instead, the refrigerant remains in a gaseous state as it absorbs heat, which is essential for the cooling process. Understanding these mechanisms clarifies why certain refrigerants are chosen based on their boiling points and thermal properties.
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Hi,

I was looking at how refrigerators and air conditioners work as part of thermodynamics and I came across the expansion valve.

I am a bit confused. From what I understand, there is this expansion valve. When the liquid freon, or ammonia as used as an example in this website, goes through the evaporator it returns to the gaseous state. But, if the gas is allowed to expand, won't it do work at the expense of it's own internal energy, and, therefore, cool, and, if it cools, how come does it become a gas and not a solid?

I think the answer why is pretty simple but I just can't see it! :redface:

Thanks in advance!
 
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It does cool but not enough to turn solid.

(this is why you don't use CO2 as a refrigerant. If you need to get down to really low temps, you use He. It won't solidify until close to zero K.)
 


But how does it boil and vaporizes? We need to heat a liquid to vaporize it, right?
 


In order for the working fluid to expand, it must absorb heat from the surroundings. This is why A/C units and refrigerators cool.
 


the heat you are talking about is taken from the things (and air) kept in the refrigerator, thus cooling them.
 
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