There are a number of processes used to make plates, but as I said, I'm most familiar with the silver halide process (similar to black & white photography). Basically, the plate is supplied with a silver halide emulsion, which is kept in the dark until use. The image to be printed is then projected (I believe now a laser image can be plotted instead) onto the plate, when the silver halide (usually silver bromide, I believe) grains are oxidised. The photochemical reaction is Ag+Br- crystals
+ hv (radiation)
--> Ag+
+ Br + e-. In short, a free Halogen atom is released when light hits the silver halide crystal. The silver ion can then combine with the electron to produce a silver atom. The free silver is what's referred to as the 'latent image'; it is this which is developed to make the visible, stable image we need.
The image then needs developing. Paraphenylendiamine (I think, check this if you need to know) is washed over the plate for a predetermined length of time in order to reduce the silver
ions back to free silver, but not long enough to allow the unexposed silver halide grains to reduce too (the ions reduce more quickly than the grains).
In order to halt the development process to produce a stable image, the image must then be fixed. Sodium Thiosulphate is used, which through a series of reactions, produces a stable, visible image on the plate.
The rest is as per my previous post.
All the reactions can be found at:
http://www.cheresources.com/photochem.shtml
Information about other plate-making technologies can be found at:
http://www.internationalpaper.com/PDF/PDFs for Papers/Offset Plate Technology.pdf