Ice added to Water (heats of rxn)

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SUMMARY

The discussion centers on a thermodynamics problem involving the heat transfer between ice and water. The user calculated the final equilibrium temperature (Tf) of a system containing 24g of ice at -5°C and 50 mL of water at 10°C, concluding that Tf equals 5.98°C. Key equations utilized include specific heat capacities for water and ice, as well as the heat of fusion for ice. The user confirmed that the heat transfer from the water to the ice during melting is equal and opposite to the heat transfer from the surroundings, validating their assumptions.

PREREQUISITES
  • Understanding of specific heat capacity (sp ht) for water and ice
  • Knowledge of the heat of fusion (dHfus) for phase changes
  • Familiarity with thermodynamic principles of heat transfer
  • Basic algebra for solving equations
NEXT STEPS
  • Study the concept of heat transfer in isolated systems
  • Learn about phase changes and their thermodynamic implications
  • Explore calculations involving specific heat capacities in different states of matter
  • Investigate the conditions under which ice melts or water freezes
USEFUL FOR

This discussion is beneficial for students studying thermodynamics, particularly those tackling heat transfer problems in chemistry or physics. It is also useful for educators looking for examples of phase change calculations.

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Homework Statement



If 24g of ice at -5C is added to a isolated dewar containing 50 mL of water at 10C. What would the temperature of the system be at equilibrium if the heat capacity can be ignored and the system is completely isolated.

Homework Equations



sp ht H2O (l) - 4.18 J/(gC)
sp ht H2O(s) = 2.01 J/(gC)

dHfus = 6.01 kJ/mol
Density H2O = 1g/ml

The Attempt at a Solution



I wasn't sure if the water would start to freeze or the ice would melt or if that is necessary to know. I approached the problem with the assumption that the ice melts and also that the transfer of heat from water to ice during melting is equal and opposite the heat transfer out of the surrounding and thus the terms cancel (I don't know if I can make this assumption). With that in mind

qrxn = -qsurr

qrxn = 24 *2.01 *(0 - (-5)) + 24*4.18*(Tf-0)

-qsurr = -50*4.18*(Tf-10)

Solving for Tf = 5.98C

My main question is if my assumptions are valid and also how would I know without it being said if the ice if going to melt of the water is going to freeze, or does it make a difference?
 
Physics news on Phys.org
Quick check is how much energy is available before the water gets down to 0C (mcT)
If this is more than the energy to melt the ice then it will be water.
 

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