Infinity potential hole - transition to base state

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The discussion focuses on calculating the probability of a particle transitioning from the first excitation state to the base state in an infinite potential well. The initial assumption is that the orthogonality of eigenfunctions implies a zero probability for this transition. However, it is clarified that external disturbances can facilitate the transition to the ground state. A reference to a related thread on hydrogen atoms provides additional insights. Overall, the conversation emphasizes the role of external factors in enabling state transitions despite theoretical constraints.
lakmus
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Hi!
I try to figure out the probability (sure as function of parameter time) of
transition particle in the hole from the first excitation state to the base
state in an infinity potential hole. Because the eigenfuncion of particle there
are orthogonal, the probability looks like zero - where could be the problem?

Thanks!
 
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There is no error at all - energy eigenstates are stable.
In reality, some external disturbance would suffice to get the electron to fall to the ground state. We discussed this briefly (for a H-atom) in this thread:
https://www.physicsforums.com/showthread.php?t=658128
(on the second page)
 
Thaks a lot for reply. The link explained it to me!
 
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