Interference of electron waves in an atomic orbital

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SUMMARY

The discussion centers on the interference of electron waves in atomic orbitals, specifically the 1s orbital. It clarifies that two electrons with opposite spins do not interfere destructively, as their wavefunctions represent distinct quantum states rather than classical waves. The state of two non-interacting electrons is expressed as \Psi (x_1, x_2) = \Psi (x_1) \Psi (x_2), indicating they occupy separate quantum states despite being in the same spatial region. Therefore, the concept of annihilation due to destructive interference is incorrect.

PREREQUISITES
  • Understanding of Quantum Mechanics principles
  • Familiarity with atomic orbitals, specifically the 1s orbital
  • Knowledge of quantum wavefunctions and their representations
  • Basic grasp of electron spin and its implications in quantum states
NEXT STEPS
  • Study the mathematical formulation of quantum wavefunctions
  • Explore the Pauli exclusion principle and its effects on electron configurations
  • Learn about the differences between quantum states and classical wave behavior
  • Investigate the implications of electron spin in multi-electron systems
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Students and professionals in physics, particularly those studying Quantum Mechanics, atomic structure, and electron behavior in atomic orbitals.

Narges
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I have a confusing question mainly due to my lack of understanding of Quantum Mechanics and spin! here it goes anyway...

In an atomic orbital, like the 1s orbital, two electron waves with opposite spins occupy the same area of space. Now, does this mean that their waves should interfere with each other?
Does the "oppositeness" of their spins mean their waves are also opposite? and if so, would this lead to destructive interference and therefore annihilation of electrons?
 
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Narges said:
I have a confusing question mainly due to my lack of understanding of Quantum Mechanics and spin! here it goes anyway...

In an atomic orbital, like the 1s orbital, two electron waves with opposite spins occupy the same area of space. Now, does this mean that their waves should interfere with each other?
Does the "oppositeness" of their spins mean their waves are also opposite? and if so, would this lead to destructive interference and therefore annihilation of electrons?

Quantum wavefunctions are not waves (as EM waves) but representations of the quantum state. The 1s orbital gives the state for a single electron in a Hydrogen atom.

For two non-interacting electrons the state is [itex]\Psi (x_1, x_2) = \Psi (x_1) \Psi (x_2)[/itex], where [itex]x_1[/itex] and [itex]x_2[/itex] are the coordinates of each electron. They are not in the «same area of space».

The response to your other questions is no, no, and no.
 
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