Internuclear axis of asymmetric axis

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The discussion centers on the concept of the internuclear axis, defined as an imaginary line connecting two nuclei in a molecule. While it is often associated with symmetry and rotation, particularly in symmetric molecules, the conversation raises the question of how to identify the internuclear axis in asymmetric molecules. It is noted that the term "internuclear" primarily refers to the geometric relationship between the nuclei rather than their rotational properties or symmetry. The idea is presented that while the internuclear axis can coincide with an axis of symmetry or serve as a rotation axis, this is not the case for all molecules, especially more complex or asymmetric ones.
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I understand internucler axis is a imaginary line about which the molecule rotates.and it's symmetric about the internucler axis.

So we can find the internucler axis by symmetry if the moecule is symmetric about some axis.



How would we find the internucler axis if the molecule is asymmetric about all the axis...?




Any help appreciated.thanks in advance.
 
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Doesn't sound to me like "internuclear" has anything to do with rotation nor symmetry, name suggests just a simple geometry - line that goes through two nuclei.

It _may_ happen that internuclear axis is an axis of symmetry, it _may_ happen that molecule rotates around it, but logic tells me these are rather exceptional situations, limited to some small and simple molecules.
 
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