Is This the Correct Thermodynamic Analysis of a Refrigerator Cycle?

AI Thread Summary
The discussion centers around the thermodynamic analysis of a refrigerator cycle, focusing on the derivation of equations related to entropy and work. The user explores the implications of the second law of thermodynamics, specifically the Clausius Inequality, and successfully derives an expression for the total entropy change. They also attempt to calculate the minimum work required for the heat pump, using the first law of thermodynamics, but struggle to reconcile their derived expression with the expected form. The key question remains whether the specific heat capacity (Cp) can be equated to the product of mass (m) and specific heat (c) to achieve the desired work expression. The analysis highlights the complexities of reversible versus irreversible cycles in thermodynamic systems.
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Homework Statement



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The Attempt at a Solution



For the first part, if we assume that the cycle is reversible from the 2nd law we have

\Delta S = \frac{\Delta Q}{T}+S_{gen} = 0

And here is the Clasius Inequality

S_{gen} \geq 0 \implies \frac{\Delta Q}{T} \leq 0

\frac{Q_x}{T_1}-\int^{T_2}_{T_1} \frac{\Delta Q}{T} \leq 0

Since ΔQ = dT

\frac{Q_x}{T_1}-\int^{T_2}_{T_1} \frac{dT}{T} = \frac{Q_x}{T_1}- \ln \frac{T_2}{T_1} \leq 0

T_2 \geq T_1e^{\frac{Q_x}{T_x}}

Since we do not know the temprature values we can't make numerical calculation of the lower limit for the final temperature of y. But did I derive the correct equation?

For the second part of the equation, to find the minimum value of work that needs to be supplied to the heat pump I tried to use the 1st Law;

Q − W = U = 0 → W = mcΔT - U

How can we use this to show the above expression for Wmin?
 
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We do not know if the cycle is reversible or irreversible. But I assumed that it is reversible because if it is not then more and more work is required due to the entropy generated.
 
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Okay, I figured out part (1) :smile:, but I'm still having some trouble working out the minimum work.

The entropy change of x is

\Delta S_x = \int^{T_2}_{T_1} C_p \frac{dT}{T} = C_p \ln \frac{T_2}{T_1}

The entropy change of y is

\Delta S_y = \int^{T_2’}_{T_1} C_p \frac{dT}{T} = C_p \ln \frac{T_2’}{T_1}

The total entropy change is

\Delta S_{tot} =\Delta S_x + \Delta S_y = C_p \ln \frac{T_2}{T_1} + C_p \ln \frac{T_2’}{T_1}

And we know from the entropy principal that ΔS ≥ 0, so

\left( C_p \ln \frac{T_2}{T_1} + C_p \ln \frac{T_2’}{T_1} \right) \geq 0

C_p \ln \frac{T_2T_2’}{T_1^2} \geq 0

The minimum value of T2’ would be

C_p \ln \frac{T_2T_2’}{T_1^2} = 0 = \ln 1

\therefore T_2’ = \frac{T_1^2}{T_2}

Okay now the minimum work:

Heat removed from x to cool it is Q=Cp (T1-T2) and the heat added to y is Q+W=Cp (T2'-T1) so

W= Cp(T2'-T1)-Cp(T1-T2)=Cp(T'2+T2-2T1)

Substituting the minimum temprature we found we end up with

W_{min} = C_p \left( \frac{T_1^2}{T_2} +T_2-2T_1 \right) = C_p \frac{(T_1-T_2)^2}{T_2}

But the expression I need is:

W_{min} = \frac{mc (T_1-T_2)^2}{T_2}

What could we do to arrive at that expression? :confused:
 
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The only way I can have:

W_{min} = C_p \frac{(T_1-T_2)^2}{T_2} = \frac{mc (T_1-T_2)^2}{T_2}

is if Cp is equal to mc. But how could this be?
 
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