Isolating Cobalt from Ore - Industrial Process

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Cobalt can be industrially isolated from its ores through various chemical processes. One method involves oxidation, where cobalt sulfide (Co2S4) reacts with oxygen to produce sulfur dioxide (SO2) and cobalt. Another common approach is roasting cobalt arsenide (CoAsS) in the presence of oxygen, resulting in cobalt oxide (Co2O3) and arsenic oxide (As2O3). The cobalt oxide can then be reduced using coal to yield elemental cobalt. Additionally, cobalt salts can be treated with ammonia to form a complex, which is subsequently reduced with hydrogen to produce powdered cobalt. This powdered cobalt can be melted in an inert atmosphere to form solid masses. Understanding these redox reactions is crucial for effective cobalt isolation.
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How do you isolate cobalt industilly from its ores? I was thinking about some oxidation:
Co_2S_4 + 4~O_2 ~ \rightarrow 4~SO_2 + Co_3

Gratefull,
Danne
 
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danne89 said:
How do you isolate cobalt industilly from its ores? I was thinking about some oxidation:
Co_2S_4 + 4~O_2 ~ \rightarrow 4~SO_2 + Co_3

Gratefull,
Danne

My textbook says that cobalt oxides are reduced with coal to give elemental cobalt, or solubilized cobalt salts are treated with ammonia to give a complex, which is then reduced with hydrogen to give powdered cobalt. The powdered cobalt is melt in an inert atmosphere to make solid masses from it.

The principal reaction is reduction with coal:

2CoAsS + 5O_2 \rightarrow Co_2O_3 + As_2O_3 + 2SO_2 (roasting; the mineral is cobaltine).

2Co_2O_3 + 3C \rightarrow 4Co + 3CO_2 (reduction with coal).

The redox reactions are my reasoning, I don't guarantee anything, so you'll have to study them by yourself first.
 
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