Kinetic energy of electron & energy states

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SUMMARY

The discussion centers on deriving the energy E0 of an electron in its lowest energy state using the kinetic energy formula E = p2/2m. The conclusion is that E0 is expressed as E0 = h2/8mL2, where L represents the length of the box confining the electron. Participants emphasized the importance of boundary conditions and the Schrödinger equation in solving the problem, indicating that the electron's wavefunction must have nodes at the box edges.

PREREQUISITES
  • Understanding of kinetic energy and momentum relationships in quantum mechanics
  • Familiarity with the Schrödinger equation
  • Knowledge of de Broglie wavelength concepts
  • Basic principles of quantum confinement in one-dimensional systems
NEXT STEPS
  • Study the Schrödinger equation for a particle in a one-dimensional box
  • Learn about boundary conditions and their implications in quantum mechanics
  • Explore de Broglie wavelength calculations and their applications
  • Investigate quantum confinement effects in various potential wells
USEFUL FOR

Students of quantum mechanics, physicists working on particle confinement, and educators teaching advanced physics concepts will benefit from this discussion.

Kognito
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Homework Statement



Use the relationship kinetic energy E = p^2/2m to show that the energy E_{0} of an electron of mass m in its lowest energy state is given by E_{0} = h^2/8mL^2


Homework Equations



E = p^2/2m

E_{0} = h^2/8mL^2


The Attempt at a Solution



I've stared at this for far too long, googled it to death as well as checked through all my course materials and I can't seem to get started with it. Any ideas at all would be welcome.

Thank you in advance,
Kognito
 
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What is L here? Is the electron in a 3d box and L is the side length? Does the problem say what boundary conditions it wants you to apply at the box edges?
 
My apologies, I missed that off the end of the sentence (too busy messing with equation formatting controls).

But yes, L represents a box within which the electron resides. The question doesn't specifically mention boundary conditions though the previous part of the question said to draw the electron in its lowest energy state, able to move freely along the length of the box, as represented by a standing wave.
 
There's two things you can do... one is write down the Schrödinger equation and then solve it.

The other is to say that the electron's wavefunction has to have nodes at the box edges, so write down an expression for its deBroglie wavelength and apply the appropriate constraints to it.
 

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