Kinetic Theory of Gases- no. of collisions

AI Thread Summary
To calculate the number of collisions per second of oxygen molecules with a 1 m² area of the vessel wall, the root mean square speed (Vrms) is essential, derived from the equation Vrms = √(3RT/M). The pressure can be expressed using the formula P = ⅓ (mN/V)(Vrms)², where m is the mass of one molecule, N is the total number of molecules, and V is the volume. The discussion emphasizes the importance of not assuming a specific shape for the vessel, suggesting a more general approach by considering a volume V instead of a cube. The calculation of collisions involves determining the total number of collisions and dividing by six for one face of the vessel. Understanding these principles is crucial for solving the problem accurately.
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Homework Statement


One mole of oxygen at 27°C and at one atmospheric pressure is enclosed in a vessel.
Assuming the molecules to be moving with Vrms, find the number of collisions per second which the molecules make with 1 m2 area of the vessel wall.

Homework Equations


vrms = √(3RT/M)
PV = nRT

The Attempt at a Solution


I want to find the total number of collisions that the molecules make with a cube of side 1m and divide that by 6 to get the no. of collisions with one face.
I know how to calculate pressure (using momentum etc), which gives the equation P = ⅓ ( mN/V ) (vrms)2 where m is the mass of one molecule, N total no. of molecules, V volume.
I don't know how to combine all this information.
 
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You combine it ONE step at a time. Your first error: you assume a 1 meter cube. Why?
 
Okay I won't. I'll assume a volume V. What next?
 
Also, do I need to even assume that it's a cube? How about I just assume a randomly shaped vessel with volume V?
 
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