Manganese Oxide mixed with HCL.

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When manganese oxide (MnO2) from an alkaline battery is mixed with hydrochloric acid (HCl), the expected reaction produces chlorine gas (Cl2) and manganese chloride (MnCl2). Manganese chloride can appear pink in its hydrated form (MnCl2 * 4 H2O). However, the discussion reveals that the observed green substance could be due to a concentrated solution of MnCl2, which may appear green under certain conditions, similar to how concentrated copper(II) salts can change color. There is some confusion regarding the color of chlorine gas, which is typically described as pale yellow-green rather than dark green. The original poster's observation of a green substance remains unclear, as they did not specify whether they were referring to a gas or a solid.
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Could someone please tell me What would be created when manganese oxide from an alkaline battery mixed with HCL? Theoretically, as far as I know, it should be pink, but I got a green substance.Thanks in advance
 
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Manganese dioxide (MnO2), from batteries, can react with hydrochloric acid (HCl) to produce chlorine gas (Cl2) and manganese chloride (MnCl2). In its hydrated form, manganese chloride tetrahydrate (MnCl2 * 4 H2O) is pink.

Perhaps when one has a very concentrated solution of MnCl2 it is green? This is just a guess, but it is the case with copper(II) salts too. For example, hydrated copper chloride forms blue solutions but very concentrated solutions appear dark green / black.
 
MnCl2 is never green. Mn(V) ions are...
 
When you add HCl to MnO2, Chlorine a dark green gas is released. Maybe that's what you saw.
 
If the amount of chlorine was large enough for a dark green color to be observed, OP would choke to death before getting to keyboard and reporting what he have seen.
 
I have personally experimented with MnO2 from a battery mixed it with Muriatic Acid and a dark green Chlorine is observed!
 
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chem101 said:
a dark green Chlorine is observed

Chlorine is not dark green. It is pale yellow-green, but not dark. No doubts it will be observed, but the color will be not dark green.

OP wasn't clear but he didn't stated "gas", nor "choking gas", so I guess he referred to the color of a solid or solution.
 
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I stand corrected. I guess thomasxc's green substance is still a mystery!
 
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