Van Laue Formulation: X-ray Diffraction from Crystal Structure

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SUMMARY

The discussion centers on the Van Laue formulation of X-ray diffraction from crystal structures, emphasizing the conditions for constructive interference of scattered rays. It establishes that for sharp intensity peaks to be observed, the path difference between rays scattered from lattice points must be an integral multiple of the wavelength. The discussion raises critical questions regarding the simultaneous scattering of wavevectors from all lattice points and the assumption of uniform wavevector magnitude for incident X-rays, challenging the conventional interpretation of interference as a phenomenon involving independent photons.

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  • Understanding of X-ray diffraction principles
  • Familiarity with wavevector notation and Bravais lattice concepts
  • Knowledge of constructive interference conditions in wave physics
  • Basic grasp of quantum mechanics related to photon behavior
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  • Study the mathematical derivation of the Van Laue equations
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Physicists, materials scientists, and students studying crystallography or X-ray diffraction techniques who seek to deepen their understanding of the Van Laue formulation and its implications in experimental setups.

amjad-sh
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When we shine an X-ray beam on a crystal, according to Van Laue formulation, for a sharp intensity peak to be observed on the screen there is a specific direction ##\mathbf{\hat{n}}## , in which for all the X-rays with wavelength ##\lambda## and wavevector ##\mathbf{k}=\dfrac{2\pi}{\lambda}\mathbf{\hat{n}}## incident on the crystal, a scattered ray will be observed in a direction ##\mathbf{\hat{n}^{'}}## with wavelength ##\lambda## and wavevector ##\mathbf{k}^{'}=\dfrac{2\pi}{\lambda}\mathbf{\hat{n}^{'}}##. This must be occurred simultaneously for all the lattice points in the crystal and the path difference between the rays scattered by each of the lattice sites in the crystal must be an integral number of wavelength.
In other words, the condition that all scattered rays will interfere constructively is that:
$$\mathbf{R} \cdot(\mathbf{k}-\mathbf{k}^{'})=2\pi m$$
for integral ##m## and all Bravaise vectors ##\mathbf{R}##.

I have two questions related to this formulation:

(1) How all the wavevectors ##\mathbf{k}^{'}## can be scattered simultaneously from all the lattice points in the same direction ##\mathbf{\hat{n}}^{'}##? Is'nt the probability for such thing to happen very low?

(2) Von Laue assumed in his formulation that all the incident X-rays will hit the lattice points with the same wavevector ##\mathbf{k}##. But we know that the atomic separation in a crystalline solid is comparable in length to the wavelength of the X-ray. Therefore, when an X-ray comes across the first plane of lattice points, it will diffract, and I think hence that the X-ray incident on the second plane of lattice points would have a wavevector with magniude different from that incident on the first plane of lattice points. Is'nt this right? So why in the Von Laue formulation it is assumed that every incident X-ray hitting the lattice points has the same magnitude ##k##?
Thanks in advance :)
Vonlaue.JPG
 
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You seem to think that interference takes place among independent multiple photons. How about rethinking it that interference talked is about a single photon ?
 
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