Chemistry Molecular orbital theory: assigning electrons

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Molecular orbital theory states that valence electrons in molecules are not assigned to individual atoms but are instead delocalized across the entire molecule. This implies that even lone pairs are not localized to specific atoms; rather, they occupy molecular orbitals that extend over the molecule. The concept emphasizes that molecular orbitals represent the collective behavior of electrons in a molecule. Understanding this delocalization is crucial for predicting molecular properties and reactivity. Overall, molecular orbitals provide a more comprehensive view of electron distribution than traditional atomic orbital models.
mcfaker
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Hello,

Is it true that according to molecular orbital theory valence electrons in molecules are not assigned to individual atoms?

Does this mean that even lone pairs are not assigned to inidividual atoms in a molecule , but rather assigned to a specified area across the molecule?


Thanks!
 
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More or less, yes.

Molecular orbitals are orbitals for the entire molecule.
 
Thanks I really appreciate your help!
 
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