Need help with a quantum chemistry problem

chemstudent09
Messages
7
Reaction score
0
I'm really struggling on even getting started on this problem. I have read the chapter several times now and I have tried to understand the explanations in the chapter. But I can't even get this problem started. All I ask is if anyone knows how to do this, can you just get me started or point me in the right direction so I can then take it from there?

Thanks for any help.

___________
Prove the theorem <K|H|L> = (N!)1/2 <KHP|H|L>

where |KHP> is the Hartree product corresponding to the determinant |K>, i.e.

|K> = |Xm(X1)Xn(X2)...>

and

|KHP> = Xm(X1)Xn(X2)...

Prove this theorem
_______________

This problem is from "Modern Quantum Chemistry" by Szabo & Ostlund for anyone who is wondering.
 
Physics news on Phys.org
I think I posted this question in the wrong part of these forums. I'm sorry about this.
 
Well, start by writing both sides out as integrals, which can be separated into sums of single-particle wave function-integrals, and see what cancels out.
 
Thread 'Need help understanding this figure on energy levels'
This figure is from "Introduction to Quantum Mechanics" by Griffiths (3rd edition). It is available to download. It is from page 142. I am hoping the usual people on this site will give me a hand understanding what is going on in the figure. After the equation (4.50) it says "It is customary to introduce the principal quantum number, ##n##, which simply orders the allowed energies, starting with 1 for the ground state. (see the figure)" I still don't understand the figure :( Here is...
Thread 'Understanding how to "tack on" the time wiggle factor'
The last problem I posted on QM made it into advanced homework help, that is why I am putting it here. I am sorry for any hassle imposed on the moderators by myself. Part (a) is quite easy. We get $$\sigma_1 = 2\lambda, \mathbf{v}_1 = \begin{pmatrix} 0 \\ 0 \\ 1 \end{pmatrix} \sigma_2 = \lambda, \mathbf{v}_2 = \begin{pmatrix} 1/\sqrt{2} \\ 1/\sqrt{2} \\ 0 \end{pmatrix} \sigma_3 = -\lambda, \mathbf{v}_3 = \begin{pmatrix} 1/\sqrt{2} \\ -1/\sqrt{2} \\ 0 \end{pmatrix} $$ There are two ways...
Back
Top