Number of moles equation in exhaust gas

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    Exhaust Gas Moles
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The discussion centers on the relationship between the number of moles of water and hydrogen in exhaust gas, with the assertion that the exhaust contains only water and no hydrocarbons. The equation presented, n_{H2O in air} = n_{H, air}/2, is debated, as it suggests that the number of water molecules is half the number of hydrogen atoms due to two hydrogen atoms per water molecule. Additionally, there is confusion regarding the appropriate molar mass to use when calculating the number of moles of hydrogen in fuel, specifically whether to use the molar mass of the fuel or that of hydrogen. Clarification is sought on whether the calculations pertain to the mole fraction of atomic hydrogen based on the mass fraction provided. The discussion highlights the complexities involved in stoichiometric calculations related to combustion and exhaust gas analysis.
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I've been given information that the exhaust gas contains only water and no HydroCarbons. So,the only hydrogen composition found in the exhaust gas is in the water.

Similarly,the hydrogen in the air coming-in is only found in the water molecules as the incoming air is pure and without any fuel.

My book hence states the equation relating the number of moles of water and number of moles of hydrogen:
∴ $$n_{H20 in air}=\frac{n_{H, air}}{2}$$

Shouldn't it be the reverse i.e 2*n_{H,air}?
 
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marellasunny said:
I've been given information that the exhaust gas contains only water and no HydroCarbons. So,the only hydrogen composition found in the exhaust gas is in the water.

Similarly,the hydrogen in the air coming-in is only found in the water molecules as the incoming air is pure and without any fuel.

My book hence states the equation relating the number of moles of water and number of moles of hydrogen:
∴ $$n_{H20 in air}=\frac{n_{H, air}}{2}$$

Shouldn't it be the reverse i.e 2*n_{H,air}?
There are two hydrogen atoms in each molecule of water, so the number of water molecules is half the number of hydrogen atoms.

Chet
 
Also,I've been given the mass fraction of the hydrogen in the fuel(h). I now want to find the number of moles of hydrogen in the fuel n_{H,fuel}. I'm confused on which molar mass(/molecular weight) to use in the equation:

$$n_{H,fuel}=\frac{mass_{H,fuel}}{M_{fuel/H?}}$$

Must I use the molar mass of the fuel or the molar mass of hydrogen?
 
marellasunny said:
Also,I've been given the mass fraction of the hydrogen in the fuel(h). I now want to find the number of moles of hydrogen in the fuel n_{H,fuel}. I'm confused on which molar mass(/molecular weight) to use in the equation:

$$n_{H,fuel}=\frac{mass_{H,fuel}}{M_{fuel/H?}}$$

Must I use the molar mass of the fuel or the molar mass of hydrogen?
Are you saying you want to find the mole fraction of atomic hydrogen in the fuel, given the mass fraction of atomic hydrogen in the fuel?

Chet
 
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