theCandyman said:
What do you mean by "energy with zero entropy"?
Candyman,
Entropy is a measure of "disorder". It is also a thermodynamic property
of matter. For example, if I tell you the density and specific energy
[ energy per unit mass ] in a material - then I've completely specified the
thermodynamic "state" of that material - including the pressure, the
temperature, and the entropy.
Anytime you transfer an incremental amount of heat energy "dQ", at a
temperature "T", then you also transfer an incremental amount of entropy
"dS" given by dQ = T dS.
So when you transfer heat energy; you transfer entropy. However, work -
like electrical energy or the mechanical energy of a spinning turbine
shaft, carries no such entropy with it. Work is "ordered" energy.
We can see how the concept of entropy affects things by considering the
following derivation of the Carnot efficiency.
Suppose we have a heat engine, working in a cycle [ the working fluid
like the water in a Rankine steam cycle is closed - so the working fluid
comes back to the same thermodynamic state at any point on the cycle].
First, from conservation of energy, we can write the following equation:
Q_in = Q_out + W
That is the sum of the waste heat out, Q_out; plus the useful work W
equals Q_in, the heat provided by the boiler, reactor,...
Now since the working fluid is in a closed cycle that comes back to the
same thermodynamic state at any point in the cycle - then there can
be no "build-up" of entropy. The entropy out has to equal the entropy
put in, plus any entropy created in the cycle. The 2nd Law of Thermodynamics
says that the amount of entropy created is non-negative [ zero or
positive]. The best you can do is to have the created entropy be zero.
But the heat engine can't decrease entropy. Therefore, we have a second
equation concerning the entropy:
S_out = S_in + S_created
The entropy out S_out that is carried by the waste heat Q_out is equal
to the entropy input S_in carried by the heat input Q_in plus any entropy
created. The 2nd law of thermodynamics states the S_created is
greater than or equal to zero - S_created >= 0.
Because of that; I'm going to turn the above equation into an inequality
as:
S_out >= S_in
Now from above, dQ = T dS; and the fact that the output entropy is
exhausted to the environment at a temperature of T_c [ the cold temp ],
we have:
Q_out = T_c S_out or S_out = Q_out / T_c
Likewise, the heat input from the boiler or reactor or whatever is at
temperature T_h [ hot temperature ], so we have
Q_in = T_h S_in or S_in = Q_in / T_h
Therefore;
Q_out / T_c >= Q_in / T_h
or turning it around:
Q_in / T_h <= Q_out / T_c
Now from the original conservation of energy equation, we know that
Q_out = Q_in - W; so we substitute that into the above to obtain:
Q_in / T_h <= ( Q_in - W ) / T_c
rearranging the above:
W/T_c <= (Q_in / T_c) - (Q_in / T_h)
Multiply both sides by T_c:
W <= Q_in - Q_in (T_c/T_h) = Q_in [ 1 - (T_c/T_h) ]
Divide both sides by Q_in:
W/Q_in <= [ 1 - (T_c/T_h) ]
Now the work out W divided by the heat input Q_in is the efficiency of
the heat engine. Therefore:
efficiency <= [ 1 - (T_c/T_h) ]
The efficiency of a heat engine is less than or equal to the quantity on
the right hand side. That is the quantity on the right hand side is a limit
on the efficiency of a heat engine - and is known as the Carnot efficiency.
Carnot efficiency = [ 1 - (T_c/T_h) ]
where T_c and T_h are temperatures on an absolute scale - either
degrees Kelvin or degrees Rankine. Since the temperatures are in a
ratio - the "size" of the units doesn't matter - any conversion factor
would divide out. All that is required is that T = 0 at absolute zero, and
not some other temperature like in the Fahrenheit and Celsius scales.
Note that nowhere did we have to specify anything about the particular
heat engine. It doesn't matter how many turbines are in the cycle, or
if reheat is used between turbines, or ... The above efficiency limit
applies to EVERY heat engine that works in a cycle.
It is because heat carries with it this entropy when ever it is transfered,
according to dQ = T dS ; that gives us this limit. Work - be it mechanical
or electrical doesn't carry entropy with it.
Therefore, a motor that converts electrical energy to mechanical
energy, or a generator that converts mechanical energy to electrical
is not bound by an efficiency limit due to the 2nd Law of Thermodynamics.
Because work doesn't carry this entropy along with it; whereas heat
energy does - work and heat are very different animals thermodynamically.
Work is a higher quality energy than is heat, because it doesn't carry
this entropy "baggage" with it. Therefore, co-mingling work and heat,
and adding them together in some ratio is of questionable use.
When two items are added together to form a sum - one can often
trade off one for the other and preserve the sum. However, with
co-mingled work and heat - you can't do that because you can't slosh
the entropy from the heat to the work component. Work will always
have zero entropy.
Dr. Gregory Greenman
Physicist