Organic chem:fractional distillation

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Discussion Overview

The discussion revolves around the process of fractional distillation of crude oil, specifically addressing the conditions under which it is heated and the behavior of alkanes at high temperatures. Participants explore the reasons for the absence of combustion during the heating process.

Discussion Character

  • Technical explanation, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant notes that crude oil is heated to about 400°C during fractional distillation without burning, questioning why lower alkanes like methane are flammable.
  • Another participant suggests that the absence of combustion is likely due to avoiding contact with air or oxygen.
  • A subsequent participant inquires whether petroleum is indeed heated in the absence of air.
  • A reply confirms that nitrogen is used to flood the columns at the start of the operation, implying an inert atmosphere.
  • Another participant questions the fate of the nitrogen in the system.
  • A response proposes that nitrogen would exit the column alongside the lighter alkanes that do not condense.

Areas of Agreement / Disagreement

Participants appear to agree on the use of nitrogen to prevent combustion, but there is some uncertainty regarding the specifics of how nitrogen interacts with the alkanes and the overall process.

Contextual Notes

There are assumptions about the behavior of gases and the conditions in the distillation column that remain unexamined, such as the exact mechanisms of nitrogen's role and the specifics of vapor behavior.

Who May Find This Useful

This discussion may be of interest to those studying organic chemistry, particularly in the context of distillation processes and the properties of hydrocarbons.

jadelamlam
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Hi,
During fractional distillation,crude oil is heated to a certain temperature,then it is pumped into the fractional tower.
As you know,petroleum is a mixture of alkanes.When it is heated in the furnace(to about 400°C),it does not burn.But lower alkanes(e.g.CH4) are extremely flammable,why it doesn't burn at 400°C?
 
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Probably because you carefully avoid contact with air or oxygen.
 
Oh,is that means,petroleum is heated with the absence of air in the furnace?
 
Yes. I suppose you flood the columns with nitrogen when you begin operation. Later on, there will be only the vapours of the various alkanes etc. in the column.
 
Where does the nitrogen go?
 
I suppose it would leave the column together with the lightes alkanes (methane, ethane) which don't condense.
 

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