Parity dependence on the orbital quantum number (l)

In summary, the angular momentum eigenfunctions in spherical coordinates are spherical harmonics, Ylm (\theta, \phi) \propto (-1)mPlm(cos\theta)eim\phi. Applying the parity operator to Ylm (\theta, \phi) results in a factor of (-1)m for eim\phi, but it is unclear how to obtain a factor of (-1)l-2m to account for the correct dependence on parity. This becomes more complicated when considering the associated Legendre polynomials, which have varying degrees of odd/evenness depending on the values of l and m.
  • #1
soccer_dude13
1
0
Hi,
I know that the angular momentum eigenfunctions in spherical coordinates are spherical harmonics, Ylm ( [tex]\theta[/tex], [tex]\phi[/tex] ) [tex]\propto[/tex] (-1)mPlm(cos[tex]\theta[/tex])eim[tex]\phi[/tex].
Applying the parity operator to Ylm ( [tex]\theta,\phi[/tex] ) means that [tex]\theta[/tex] -> [tex]\pi[/tex] - [tex]\theta[/tex] and [tex]\phi[/tex] -> [tex]\phi[/tex] +[tex]\pi[/tex].
This implies that eim[tex]\phi[/tex] will pick up a (-1)m factor. However, from the definition of the Plm(cos[tex]\theta[/tex])'s I don't see how I can pick up a factor of (-1)l-2m in order to give parity the final correct dependence of (-1)l. In fact I don't see how we can creep up a dependence on l, at all.
 
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  • #2
Consider first the special case of the P_ll, i.e. the case with m=l. The P_ll are just the ordinary Legendre functions which are even polynomials in x=cos theta for even l and odd polynomials for odd l. The associated Legendre Polynomials P_lm contain m further derivatives with respect to x so that the odd/evenness changes with m.
 

1. What is parity dependence on the orbital quantum number (l)?

Parity dependence on the orbital quantum number (l) is a concept in quantum mechanics that describes the behavior of particles and their wave functions based on their orbital quantum number. It refers to the symmetry properties of a particle's wave function under spatial inversion, where the coordinates are changed from (x, y, z) to (-x, -y, -z).

2. How does the orbital quantum number (l) affect parity?

The orbital quantum number (l) determines the angular momentum of a particle, and it plays a crucial role in determining the parity of a particle. Parity is dependent on the value of l, and it can be either even or odd. This means that the wave function of a particle with an even value of l will remain unchanged after spatial inversion, while the wave function of a particle with an odd value of l will change sign.

3. What is the significance of parity dependence on the orbital quantum number (l)?

Understanding the parity dependence on the orbital quantum number (l) is essential in predicting the behavior of particles in quantum systems. It helps in determining the symmetry properties and selection rules for various physical processes, such as transitions between energy levels and emission of photons. Additionally, it has significant implications in atomic and molecular physics, as well as in nuclear and particle physics.

4. What are the possible values of the orbital quantum number (l)?

The orbital quantum number (l) can have integer values ranging from 0 to n-1, where n is the principal quantum number of an electron. This means that for a given energy level, the possible values of l can be 0, 1, 2, 3, and so on up to n-1. For example, in the n=2 energy level, l can have values of 0 and 1, while in the n=3 energy level, l can have values of 0, 1, and 2.

5. How does parity dependence on the orbital quantum number (l) relate to the shape of atomic orbitals?

The parity dependence on the orbital quantum number (l) is closely related to the shape of atomic orbitals. This is because the value of l determines the angular momentum and the shape of the orbital. For example, s orbitals have a value of l=0 and are spherically symmetric, while p orbitals have a value of l=1 and are dumbbell-shaped. The parity of these orbitals also follows the same pattern, with s orbitals having even parity and p orbitals having odd parity.

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